correction, dion says he wants to see her cry but more like wants her to dote on him, so she's guessing he wants to have sex with her too, but they haven't. he's acting as her loyal dog as long as she gives him the bare minimum of affection (even when she says she hates him, she still pets him in weird ways).
fontaine totally wants to fuck her, and is willing to marry her when he becomes the heir (just his delusion though). she is giving fontaine mixed signals to have him act as she wants him to.
the only one she's slept with so far is the ML that one time, she just makes others want her so that they'll be willing to do everything she asks for, for a chance to be with her

I find the sexual tension weird.. like aren't they siblings or am I mistaken? and tbh I don't really see the sexual tension lol