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Yes. It was revealed starting at the end of episode 95 through now. Carcel was her first husband. That’s why the manhwa is called The Broken Ring. It’s talking about their marriage that has been broken and needs to be fixed.
Ines didn’t remember at all because she wasn’t supposed to remember. Go back to the end of ep95 and beginning of ep96 and you will see it’s the Apostle Anastasio that gave her back the memories. Carcel also realized that Ines was his first wife during the Bilbao arc when he slammed his forehead on the ground and he started to bleed.

Wait, they were also married in the past life?? Novel reader pls tell me!!!!