Responses
Spoilers ahead
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Arsian is ml. Rainer is her brother. Adopted, yeah, but there's no romance, he really is just cool reliable bro.
Prince is not a real candidate. I'd say he's a problem Camilla needs to solve (the emperor - the main bad guy - for centuries pretty much concider his kids as spare bodies to move his soul into to live forever).

Hey, guys. Who is the ML?
Arsen? Rainer? Prince?
Any novel readers around?